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Crystallographic report: (η 5 ‐C 5 Me 5 )Fe(CO) 2 (BOCH 2 CH 2 CH 2 O): an organoiron complex containing the (trimethyleneglycolato)boryl ligand
Author(s) -
Rossin Andrea,
Aldridge Simon,
Ooi Liling
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.739
Subject(s) - chemistry , ligand (biochemistry) , planar , crystallography , stereochemistry , receptor , biochemistry , computer graphics (images) , computer science
The structure of the pentamethylcyclopentadienyliron boryl complex (η 5 ‐C 5 Me 5 )Fe(CO) 2 B(tmg) (tmg = trimethylene glycolato, OCH 2 CH 2 CH 2 O), reveals a planar three‐coordinate boryl ligand and an FeB distance significantly in excess of that reported for related catecholboryl complexes. Copyright © 2005 John Wiley & Sons, Ltd.
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