Premium
Synthesis of phenyl arsenic analytical standards related to contaminated well water in Kamisu, Ibaraki, Japan
Author(s) -
Nakamiya Kunichika,
Shibata Yasuyuki,
Ito Hiroyasu,
Edmonds John S.,
Morita Masatoshi
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.719
Subject(s) - chemistry , arsenic , liquid ammonia , contamination , sodium , ammonia , inorganic chemistry , environmental chemistry , nuclear chemistry , organic chemistry , ecology , biology
To facilitate, by the provision of internal standards, the liquid chromatographic and mass spectrometric analysis of diphenylarsinic acid in well water and other samples related to an incident of environmental contamination in Kamisu, Ibaraki, Japan, syntheses of the analogous perdeuterated and mono‐ meta ‐ and di‐ meta ‐methylated acids were undertaken. The acids were synthesized by cleavage of the triarylarsines by sodium in liquid ammonia. The triarylarsines were made from the reaction of arsenous chloride and sodium with the appropriate aryl‐bromo compound. Properties of the compounds are given. Copyright © 2005 John Wiley & Sons, Ltd.