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A novel phenyl–bromine ligand exchange reaction on germanium by boron tribromide
Author(s) -
Takeuchi Yoshito,
Suzuki Kazuyuki,
Yagi Takashi,
Yoshida Yusuke,
Suzuki Yoshitake
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.718
Subject(s) - chemistry , bromine , germanium , ligand (biochemistry) , boron , medicinal chemistry , photochemistry , organic chemistry , silicon , biochemistry , receptor
A novel phenyl–bromine ligand exchange reaction by BBr 3 on germanium was investigated that proceeds without breaking GeCH 2 Ar bond. Typically, the reaction between (PhCH 2 ) 3 PhGe and BBr 3 resulted exclusively in the formation of (PhCH 2 ) 3 GeBr. Copyright © 2005 John Wiley & Sons, Ltd.
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