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Crystallographic report: Diaqua(benzene‐1,4‐dioxyacetate)zinc(II): a one‐dimensional zigzag chain
Author(s) -
Gao Shan,
Liu JiWei,
Huo LiHua,
Zhao Hui,
Ng Seik Weng
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.688
Subject(s) - zigzag , chemistry , zinc , crystallography , crystal structure , benzene , hydrogen bond , chain (unit) , ion , atom (system on chip) , molecule , geometry , organic chemistry , physics , mathematics , astronomy , computer science , embedded system
The zinc(II) atom in the crystal structure of the title coordination polymer, [Zn( p ‐BDOA)·2H 2 O] n ( p ‐BDOA 2− = benzene‐1,4‐dioxyacetate), exists in a distorted trigonal prismatic geometry. Adjacent zinc(II) ions are linked by the p ‐BDOA 2− ligands to furnish a one‐dimensional (1‐D) zigzag chain. A three‐dimensional (3‐D) network structure is stabilized by extended hydrogen bonds. Copyright © 2004 John Wiley & Sons, Ltd.