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Crystallographic report: A polymorph of undecasodium decatrimethylsilanolate hydroxide: [Na 11 (OSiMe 3 ) 10 (OH)]
Author(s) -
Mehring Michael,
Nolde Christof,
Schürmann Markus
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.684
Subject(s) - chemistry , square antiprism , crystallography , toluene , sodium , crystal structure , sodium hydroxide , molecule , inorganic chemistry , organic chemistry , oxygen atom
The title compound is a polymorph of [Na 11 (OSiMe 3 ) 10 (OH)] and was crystallized from a toluene solution containing NaOSiMe 3 and water. The molecular structure is best described as being composed of two subunits, a square antiprism built from eight sodium atoms and an Na 4 O 4 heterocubane, both sharing a sodium atom. Copyright © 2004 John Wiley & Sons, Ltd.