Crystallographic report: Octameric sodium trimethylsilanolate hemihydrate hemi‐THF solvate, [ $\hbox{NaOSiMe}_{3}{ \cdot} {1 \over 2} \hbox{H}_{2}\hbox{O}{\cdot} {1 \over 2}$THF ] 8 | Zendy

Mehring Michael | Zendy; Nolde Christof | Zendy; Schürmann Markus | Zendy

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Crystallographic report: Octameric sodium trimethylsilanolate hemihydrate hemi‐THF solvate, [ $\hbox{NaOSiMe}_{3}{ \cdot} {1 \over 2} \hbox{H}_{2}\hbox{O}{\cdot} {1 \over 2}$THF ] 8

Author(s) -

Mehring Michael,

Nolde Christof,

Schürmann Markus

Publication year - 2004

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.683

Subject(s) - chemistry , crystallography , hemihydrate , oxygen atom , molecule , hydrogen bond , cube (algebra) , group (periodic table) , crystal structure , stereochemistry , combinatorics , organic chemistry , gypsum , paleontology , mathematics , biology

The title compound is composed of two Na 4 O 4 heterocubanes which are connected via four µ‐OSiMe 3 groups. The oxygen atoms of the water molecules occupy two corners of an Na 4 O 4 cube and additionally form hydrogen bonds to the µ‐OSiMe 3 groups with O·O distances in the range 2.649(4)–2.714(4) Å. Copyright © 2004 John Wiley & Sons, Ltd.

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