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Crystallographic report: [(η 5 ‐C 5 H 5 )Fe(CO) 2 ] 2 Ga 3 Cl 3 (OSiMe 2 OSiMe 2 O) 2 : a diiron complex of a tetracyclic trigallasiloxane
Author(s) -
Bunn Natalie R.,
Aldridge Simon,
Jones Cameron
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.675
Subject(s) - chemistry , gallium , crystallography , x ray crystallography , bond length , group 2 organometallic chemistry , crystal structure , metal , stereochemistry , molecule , physics , diffraction , organic chemistry , optics
The structure of the penta‐metallic diiron trigallasiloxane, [(η 5 ‐C 5 H 5 )Fe(CO) 2 ] 2 Ga 3 Cl 3 (OSiMe 2 OSiMe 2 O) 2 , reveals two distinct gallium coordination environments and FeGa bond lengths (2.3258(6) Å), consistent with bonding of the iron centres to four‐coordinate gallyl ligands. Copyright © 2004 John Wiley & Sons, Ltd.