Crystallographic report: [(η 5 ‐C 5 H 5 )Fe(CO) 2 ] 2 Ga 3 Cl 3 (OSiMe 2 OSiMe 2 O) 2 : a diiron complex of a tetracyclic trigallasiloxane | Zendy

Bunn Natalie R. | Zendy; Aldridge Simon | Zendy; Jones Cameron | Zendy

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Crystallographic report: [(η 5 ‐C 5 H 5 )Fe(CO) 2 ] 2 Ga 3 Cl 3 (OSiMe 2 OSiMe 2 O) 2 : a diiron complex of a tetracyclic trigallasiloxane

Author(s) -

Bunn Natalie R.,

Aldridge Simon,

Jones Cameron

Publication year - 2004

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.675

Subject(s) - chemistry , gallium , crystallography , x ray crystallography , bond length , group 2 organometallic chemistry , crystal structure , metal , stereochemistry , molecule , physics , diffraction , organic chemistry , optics

The structure of the penta‐metallic diiron trigallasiloxane, [(η 5 ‐C 5 H 5 )Fe(CO) 2 ] 2 Ga 3 Cl 3 (OSiMe 2 OSiMe 2 O) 2 , reveals two distinct gallium coordination environments and FeGa bond lengths (2.3258(6) Å), consistent with bonding of the iron centres to four‐coordinate gallyl ligands. Copyright © 2004 John Wiley & Sons, Ltd.

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