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Crystallographic report: Bis(η 5 ‐methyl‐cyclopentadienyl)‐bis(cyanato)‐vanadium(IV)
Author(s) -
Honzíček Jan,
Erben Milan,
Císařová Ivana,
Vinklárek Jaromír
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.663
Subject(s) - cyclopentadienyl complex , chemistry , vanadium , bent molecular geometry , crystal structure , molecule , metallocene , crystallography , stereochemistry , inorganic chemistry , catalysis , organic chemistry , polymerization , polymer
The crystal structure of the first cyclopentadienyl vanadium(IV) pseudohalide complex, (η 5 ‐C 5 H 4 CH 3 ) 2 V(NCO) 2 , was determined. The molecule has a typical bent metallocene structure in which two η 5 ‐bonded methyl‐cyclopentadienyl rings and two nitrogen atoms of cyanato ligands occupy the pseudotetrahedral coordination sites around the vanadium(IV) center. Copyright © 2005 John Wiley & Sons, Ltd.