Crystallographic report: Bis(η 5 ‐methyl‐cyclopentadienyl)‐bis(cyanato)‐vanadium(IV) | Zendy

Honzíček Jan | Zendy; Erben Milan | Zendy; Císařová Ivana | Zendy; Vinklárek Jaromír | Zendy

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Crystallographic report: Bis(η 5 ‐methyl‐cyclopentadienyl)‐bis(cyanato)‐vanadium(IV)

Author(s) -

Honzíček Jan,

Erben Milan,

Císařová Ivana,

Vinklárek Jaromír

Publication year - 2005

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.663

Subject(s) - cyclopentadienyl complex , chemistry , vanadium , bent molecular geometry , crystal structure , molecule , metallocene , crystallography , stereochemistry , inorganic chemistry , catalysis , organic chemistry , polymerization , polymer

The crystal structure of the first cyclopentadienyl vanadium(IV) pseudohalide complex, (η 5 ‐C 5 H 4 CH 3 ) 2 V(NCO) 2 , was determined. The molecule has a typical bent metallocene structure in which two η 5 ‐bonded methyl‐cyclopentadienyl rings and two nitrogen atoms of cyanato ligands occupy the pseudotetrahedral coordination sites around the vanadium(IV) center. Copyright © 2005 John Wiley & Sons, Ltd.

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