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Synthesis of ferrocenoylphenylureas and the crystal structure of FcCONHCONHC 6 H 5
Author(s) -
Chen Li,
Wang Qingmin,
Huang Runqiu,
Mao Chunhui,
Shang Jian,
Song Haibin
Publication year - 2005
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.652
Subject(s) - chemistry , phenylisocyanate , moiety , mass spectrometry , crystal structure , elemental analysis , nuclear magnetic resonance spectroscopy , ferrocene , stereochemistry , organic chemistry , chromatography , electrode , electrochemistry
We replaced the benzoyl moiety by ferrocenoyl in benzoylphenylurea, and synthesized a series of new benzoylphenylureas containing a ferrocenyl moiety by the reaction of carbamylferrocene with phenylisocyanate in good yields. The title compounds were identified by IR, 1 H NMR spectroscopy, electron‐impact mass spectrometry and elemental analyses. The crystal structure of 1‐ferrocenoyl‐3‐phenylurea was determined. The bioactivities of the new compounds were also determined. Copyright © 2005 John Wiley & Sons, Ltd.