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Crystallographic report: A synthetic precursor for hetero‐binuclear metal complexes, [Ru(bpy)(dppy) 2 (CO) 2 ](PF 6 ) 2 (bpy = 2,2′‐bipyridine, dppy = 2‐(diphenylphosphino)pyridine)
Author(s) -
Ooyama Dai,
Sato Masahito
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.637
Subject(s) - chemistry , ruthenium , pyridine , octahedron , bipyridine , 2,2' bipyridine , nitrogen atom , crystallography , metal , stereochemistry , atom (system on chip) , center (category theory) , crystal structure , medicinal chemistry , catalysis , ring (chemistry) , organic chemistry , computer science , embedded system
In the title complex, [Ru(bpy)(dppy) 2 (CO) 2 ](PF 6 ) 2 (bpy = 2,2′‐bipyridine, dppy = 2‐(diphenylphosphino)pyridine), the ruthenium atom exhibits a slightly distorted octahedral coordination with the carbonyl ligands in cis positions. In addition, two dppy ligands coordinate to the ruthenium center through the phosphorus atoms in mutually trans positions and two pyridyl nitrogen atoms of the dppy direct toward two carbonyl ligands. Copyright © 2004 John Wiley & Sons, Ltd.