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Iridium‐catalyzed asymmetric hydrogenation of β‐ketophosphonates with chiral ferrocenyl P,N,N‐ligands
Author(s) -
Ma YinFeng,
Hou ChuanJin,
Wei DeQuan,
He Xinwei,
Chu TingTing,
Chen Xiushuai,
Hu XiangPing
Publication year - 2021
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.6283
Subject(s) - chemistry , iridium , catalysis , asymmetric hydrogenation , enantioselective synthesis , medicinal chemistry , combinatorial chemistry , organic chemistry
The asymmetric hydrogenation of β‐ketophosphonates with chiral Ir/P,N,N‐ligands catalyst has been developed. A series of β‐ketophosphonates were hydrogenated, and the corresponding β‐hydroxyphosphonates were obtained in high yields with good or excellent enantioselectivities under mild condition.