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Crystallographic report: Bis{[diacetyl‐bis(2,6‐isopropylphenylimine)]nickel(I)(µ‐chloro)}
Author(s) -
Shao Qing,
Sun Hongmei,
Shen Qi,
Zhang Yong
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.624
Subject(s) - chemistry , diimine , nickel , diacetyl , chelation , crystal structure , crystallography , stereochemistry , chlorine , inorganic chemistry , organic chemistry , catalysis
The first α‐diimine nickel(I) complex having a chloro bridge is reported. The centrosymmetric dinuclear structure of {[ArNC(Me)C(Me)NAr]NiCl} 2 [Ar2,6−C 6 H 3 (i‐Pr) 2 ] features two chelating α‐diimine ligands and two bridged chlorine atoms, so that a distorted tetrahedral N 2 Cl 2 coordination geometry for nickel results. Copyright © 2004 John Wiley & Sons, Ltd.