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Magnetite@MCM‐41 nanoparticles as support material for Pd‐ N ‐heterocyclic carbene complex: A magnetically separable catalyst for Suzuki–Miyaura reaction
Author(s) -
Akkoç Mitat,
Buğday Nesrin,
Altın Serdar,
Yaşar Sedat
Publication year - 2021
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.6233
Subject(s) - catalysis , magnetite , thermogravimetric analysis , chemistry , x ray photoelectron spectroscopy , fourier transform infrared spectroscopy , palladium , coupling reaction , heterogeneous catalysis , nuclear chemistry , inorganic chemistry , organic chemistry , chemical engineering , materials science , metallurgy , engineering
The Magnetite@MCM‐41@NHC@Pd catalyst was obtained with Pd metal bound to the NHC ligand anchored to the surface of Fe 3 O 4 @MCM‐41. It was characterized by Fourier transform infrared (FTIR) spectroscopy, transmission electron microscopy (TEM), X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), energy disperse X‐ray analysis (EDX), thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy (SEM). The amount of Pd in the Magnetite@MCM‐41@NHC@Pd was measure by inductively coupled plasma–optical emission spectroscopy (ICP‐OES) analysis. The catalytic activity of Magnetite@MCM‐41@NHC@Pd heterogeneous catalyst done on Suzuki–Miyaura reactions of aryl halides with different substituted arylboronic acid derivatives. All coupling reactions afforded excellent yields and up to 408404 Turnover Frequency (TOF) h −1 in the presence of 2 mg of Magnetite@MCM‐41@NHC@Pd catalyst (0.0564 mmol g −1 , 0.01127 mmol% Pd) at room temperature in 2‐propanol/H 2 O (1:2). Moreover, Magnetite@MCM‐41@NHC@Pd catalyst was recover by applying the magnet and reused for another reaction. The catalyst showed excellent structural and chemical stability and reused ten times without a substantial loss in its catalytic performance.