Premium
The capable Pd complex immobilized on the functionalized polymeric scaffold for the green benzylation reaction
Author(s) -
Ariannezhad Maryam,
Habibi Davood,
Heydari Somayyeh,
Khorramabadi Vahideh
Publication year - 2021
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.6208
Subject(s) - chemistry , bromide , serratia marcescens , bacteria , catalysis , antibacterial activity , benzyl chloride , benzyl bromide , nuclear chemistry , polymer , organic chemistry , combinatorial chemistry , escherichia coli , biochemistry , genetics , biology , gene
The Pd complex immobilized on the functionalized polymeric support was prepared by the functionalization of the 4‐(benzyloxy)benzyl chloride polymer with 5‐phenyl‐1‐ H ‐tetrazole and the subsequent complexation with PdCl 2 . Then, it was characterized with different methods and used as catalyst in the green benzylation reaction of various aryl cyanamides with benzyl bromide and K 2 CO 3 in EtOH at 60°C for the appropriate times. Also, the antibacterial properties of the Pd polymer‐supported complex were studied against a number of gram‐positive and gram‐negative bacteria, and in some cases, it has the same effect as a tetracycline standard antibiotic against Bacillus thuringiensis (a gram‐positive bacterium) and Serratia marcescens (a gram‐negative bacterium).