Coordination behaviour of the 2‐( N , N ‐dimethylaminomethyl)phenyl ligand towards the di‐t‐butylchlorotin(IV) moiety | Zendy

Novák Petr | Zendy; Císařová Ivana | Zendy; Jambor Roman | Zendy; Rûžička Aleš | Zendy; Holeček Jaroslav | Zendy

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Coordination behaviour of the 2‐( N , N ‐dimethylaminomethyl)phenyl ligand towards the di‐t‐butylchlorotin(IV) moiety

Author(s) -

Novák Petr,

Císařová Ivana,

Jambor Roman,

Rûžička Aleš,

Holeček Jaroslav

Publication year - 2004

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.615

Subject(s) - chemistry , steric effects , moiety , ligand (biochemistry) , tin , intramolecular force , halide , trigonal bipyramidal molecular geometry , chelation , stereochemistry , medicinal chemistry , chloride , coordination complex , crystallography , crystal structure , inorganic chemistry , metal , organic chemistry , biochemistry , receptor

{2‐( N , N ‐Dimethylaminomethyl)phenyl}(di‐t‐butyl)tin(IV)chloride, {2‐[(CH 3 ) 2 NCH 2 ]C 6 H 4 }Sn(t‐Bu) 2 Cl, has been prepared and characterized using NMR and crystallography. This is the first example of a triorganotin(IV) halide containing the 2‐[(CH 3 ) 2 NCH 2 ]C 6 H 4 —group as a C,N‐chelating ligand with a weak intramolecular Sn—N interaction because of the steric hindrance of t‐butyl groups. The interatomic Sn—N distance is elongated to 2.904(14) Å and the central tin atom is distorted trigonal bipyramidal. Copyright © 2004 John Wiley & Sons, Ltd.

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