Premium
Coordination behaviour of the 2‐( N , N ‐dimethylaminomethyl)phenyl ligand towards the di‐t‐butylchlorotin(IV) moiety
Author(s) -
Novák Petr,
Císařová Ivana,
Jambor Roman,
Rûžička Aleš,
Holeček Jaroslav
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.615
Subject(s) - chemistry , steric effects , moiety , ligand (biochemistry) , tin , intramolecular force , halide , trigonal bipyramidal molecular geometry , chelation , stereochemistry , medicinal chemistry , chloride , coordination complex , crystallography , crystal structure , inorganic chemistry , metal , organic chemistry , biochemistry , receptor
{2‐( N , N ‐Dimethylaminomethyl)phenyl}(di‐t‐butyl)tin(IV)chloride, {2‐[(CH 3 ) 2 NCH 2 ]C 6 H 4 }Sn(t‐Bu) 2 Cl, has been prepared and characterized using NMR and crystallography. This is the first example of a triorganotin(IV) halide containing the 2‐[(CH 3 ) 2 NCH 2 ]C 6 H 4 —group as a C,N‐chelating ligand with a weak intramolecular Sn—N interaction because of the steric hindrance of t‐butyl groups. The interatomic Sn—N distance is elongated to 2.904(14) Å and the central tin atom is distorted trigonal bipyramidal. Copyright © 2004 John Wiley & Sons, Ltd.