Premium
Higher temperature order–disorder transition, electrical and optical properties of [N(C 2 H 5 ) 4 ] 2 Pd 2 Cl 6 compound
Author(s) -
Dakhlaoui I.,
Karoui K.,
Hajaloui F.,
Jomni F.
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5990
Subject(s) - chemistry , orthorhombic crystal system , polaron , analytical chemistry (journal) , electrical resistivity and conductivity , x ray crystallography , band gap , dielectric spectroscopy , atmospheric temperature range , diffraction , condensed matter physics , crystallography , crystal structure , electrode , thermodynamics , electron , electrochemistry , optics , physics , chromatography , quantum mechanics
[N(C 2 H 5 ) 4 ] 2 Pd 2 Cl 6 hybrid compound with semiconducting character was synthetized and characterized by X‐ray diffraction, the thermal, optical and electrical properties. X‐ray diffraction indicates that the compound crystallize at room temperature in the orthorhombic system and (Immm) space group. Two endothermic peaks at, 343 K and 440 K were observed in the DSC measurements corresponding to the evaporation of water molecules and order‐disorder transition, respectively. The optical band gap (E g = 4.34 eV) was deduced by the Tauc relation. The electrical properties was studied using the impedance spectroscopy in the frequency range of 0.1 Hz to 1 MHz and over the temperature range of 270 K to 480 K. The analysis of Nyquist plots revealed the presence of grains, grain boundaries and the electrode effects. The equivalent circuit was determined. The Ac conductivity was analyzed by the Jonsher low and the conduction mechanism was deduced based in the Elliot theory and indicate that the correlated barrier hopping model (CBH) was described the two regions II and IV and the overlapping polaron model (OLPT) the right model described the conduction in the regions I and III.