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Crystallographic report: Bis[bis( N ‐methyl‐ N ‐phenyldithiocarbamato)‐(methylxanthato)bismuth(III)]
Author(s) -
Yin HanDong,
Wang ChuanHua,
Wang Yong
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.597
Subject(s) - dithiocarbamate , chemistry , xanthate , pentagonal bipyramidal molecular geometry , bismuth , bipyramid , chelation , intermolecular force , crystallography , coordination geometry , crystal structure , stereochemistry , molecule , inorganic chemistry , organic chemistry , hydrogen bond
The centrosymmetric structure of {Bi[S 2 CN(Me)Ph] 2 (S 2 COMe)} 2 features chelating dithiocarbamate and xanthate ligands, as well as intermolecular Bi·S interactions, so that a distorted pentagonal bipyramidal S 7 coordination geometry results. Copyright © 2004 John Wiley & Sons, Ltd.
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