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NCC Pincer Ni (II) Complexes Catalyzed Hydrophosphination of Nitroalkenes with Diphenylphosphine
Author(s) -
Yan Jing,
Wang YanBing,
Hou Senyao,
Shi Linlin,
Zhu Xinju,
Hao XinQi,
Song MaoPing
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5954
Subject(s) - chemistry , diphenylphosphine , pincer movement , catalysis , yield (engineering) , medicinal chemistry , organic chemistry , phosphine , materials science , metallurgy
An efficient NCC pincer Ni (II)‐catalyzed hydrophosphination of nitroalkenes with diphenylphosphine has been developed. Under the optimized conditions, both (hetero)aromatic and aliphatic nitroalkenes were well tolerated, irrespective of electronic effect, to provide the corresponding products in up to 99% yield.