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Dissolved butyltins in marine waters of the netherlands three years after the ban
Author(s) -
Ritsema R.
Publication year - 1994
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590080103
Subject(s) - tributyltin , biofouling , chemistry , environmental chemistry , seawater , sediment , dredging , biocide , oceanography , geology , organic chemistry , paleontology , biochemistry , membrane
In 1990 the Dutch government banned the use of tributyltin‐containing antifouling paint for ships up to 25m long. Concentrations of dissolved (<0.45 μm) tributyltin and its degradation products di‐ and mono‐butyltin were determined in six selected marinas during three consecutive years with a frequency of five times a year, starting in 1990. The highest butyltin concentrations were found in Scharendijke located in the salt water lake Grevelingen: up to 2500 ng dm −3 . In tidal‐water marinas butyltin concentrations were in the order of 50–300 ng dm −3 , depending on the boating and dredging activity. In some marinas higher butyltin concentrations were found during the summer period, probably indicating the illegal use of tributyltin‐containing antifouling paints. No clear trend of decrease in dissolved tributyltin concentrations in the different marinas has been found. Due to the equilibrium between the butyltins dissolved in the water and the butyltins adsorbed onto the sediment, water concentrations will remain more or less constant.