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The use of sodium tetraethylborate in the derivatization of octyltin compounds
Author(s) -
Craig Peter J.,
Mennie Darren
Publication year - 1994
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590080102
Subject(s) - chemistry , derivatization , yield (engineering) , sodium , chromatography , nuclear chemistry , organic chemistry , mass spectrometry , materials science , metallurgy
Octyltin trichloride (OctSnCl 3 ) and dioctyltin dichloride (Oct 2 SnCl 2 ) have been reacted with sodium tetraethylborate (NaBEt 4 ) to yield the volatile tetraalkyltin derivatives OctSnEt 3 and Oct 2 SnEt 2 . Single and mixed solutions of the octyltin chlorides have been derivatized, separated and quantified using interfaced GC AA and GC MS methodology.