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Studies on binuclear Schiff base derivatives having a SiOSb (V) linkage
Author(s) -
Chaturvedi Vibhav,
Tandon J P,
Chaturvedi Laxmi
Publication year - 1992
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590060607
Subject(s) - chemistry , monobasic acid , schiff base , denticity , antimony , hexa , ligand (biochemistry) , monomer , silicon , crystallography , stereochemistry , inorganic chemistry , polymer chemistry , organic chemistry , crystal structure , biochemistry , receptor , polymer
Schiff base derivatives of the type Ph 3 SiOSb(NO)Ph 3 (where NO represents the donor system of a monobasic bidentate ligand) have been synthesized. These are obtained as coloured solids; they are non‐electrolytes and monomeric in nature, and have been characterized by elemental analysis, IR and 1 H NMR. Spectral studies suggest that silicon and antimony atoms are in tetra‐ and hexa‐coordinated states, respectively.