Alkane activation by homogeneous palladium complexes | Zendy

Beattie James K | Zendy; Masters Anthony F | Zendy; Sparkes Meredith L | Zendy

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Alkane activation by homogeneous palladium complexes

Author(s) -

Beattie James K,

Masters Anthony F,

Sparkes Meredith L

Publication year - 1991

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.590050611

Subject(s) - chemistry , palladium , adamantane , trifluoroacetic acid , yield (engineering) , homogeneous , hydrolysis , nitrogen , alkane , organic chemistry , polymer chemistry , catalysis , materials science , physics , metallurgy , thermodynamics

The conversion of adamantane exclusively to 1‐adamantyl trifluoroacetate in a refluxing trifluoroacetic acid solution of palladium acetate at 1 atm of air or nitrogen was confirmed. The conversion can be made quantitative. The 1‐adamantyl trifluoroacetate was hydrolysed to yield 1‐adamantanol in 90% isolated yield. The adamantane functionalization is accompanied by concomitant formation of a palladium mirror.

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