The synthesis of heteronuclear transition‐metal clusters derived from methylidyne tricobalt cluster precursors: The reaction of Mn(CO)       5    −     with (μ 3 ‐CCl)Co 3 (CO) 7 (μ‐dppm). The crystal and molecular structure of (μ 3 ‐CH)Co 2 Mn(CO) 8 (μ‐dppm), a methylidyne cluster containing a seven‐coordinate manganese atom | Zendy

Duffy D Neil | Zendy; Kassis Maram M | Zendy; Rae A David | Zendy

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The synthesis of heteronuclear transition‐metal clusters derived from methylidyne tricobalt cluster precursors: The reaction of Mn(CO) 5 − with (μ 3 ‐CCl)Co 3 (CO) 7 (μ‐dppm). The crystal and molecular structure of (μ 3 ‐CH)Co 2 Mn(CO) 8 (μ‐dppm), a methylidyne cluster containing a seven‐coordinate manganese atom

Author(s) -

Duffy D Neil,

Kassis Maram M,

Rae A David

Publication year - 1990

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.590040505

Subject(s) - chemistry , manganese , heteronuclear molecule , cluster (spacecraft) , transition metal , crystallography , metal , cluster chemistry , rhenium , carbyne , inorganic chemistry , stereochemistry , nuclear magnetic resonance spectroscopy , catalysis , carbene , organic chemistry , computer science , programming language

The reaction of manganese pentacarbonyl anion with chloromethylidyne tricobaltnonacarbonyl, (μ 3 ‐CCl)Co 3 (CO) 9 , leads to reduction of the cluster with formation of Mn 2 (CO) 10 and Co(CO) 4 − , whilst reaction of Mn(CO) 5 −with the bis(diphenylphosphino)methane (dppm)‐stabilised cluster (μ 3 ‐CCl)Co 3 (CO) 7 (μ‐dppm) leads to the formation of (μ 3 ‐CH)Co 2 Mn(CO) 8 (μ‐dppm), 1. The unique feature of the structure of 1 is the incorporation of a seven‐coordinate manganese atom into the metal triangle.

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