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Reactivity of isopropenylacetylene, HCCC(CH 3 )CH 2 , in the presence of the complex [Ni(NCS) {CCC(CH 3 )CH 2 }(PPh 3 ) 2 ]
Author(s) -
Furlani A.,
Russo M. V.
Publication year - 1990
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590040404
Subject(s) - chemistry , reactivity (psychology) , tris , mass spectrum , medicinal chemistry , oxygen , crystallography , polymer chemistry , organic chemistry , ion , medicine , biochemistry , alternative medicine , pathology
The reactivity of isopropenylacetylene (IP) in the presence of [Ni(NCS){CCC(CH 3 )CH 2 }(PPh 3 ) 2 ] has been examined. 1,2,4‐Tris(isopropenyl)benezene (1,2,4‐TIB), two isomeric tetramers formed by reaction of 1,2,4‐TIB with IP, and polymeric fractions have been separated and characterized by IR, NMR and mass spectra. Stability of reaction products towards oxygen and humidity has also been investigated.