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Thermal decomposition of butylindium thiolates and preparation of indium sulfide powders
Author(s) -
Nomura Ryoki,
Inazawa Shin'ji,
Kanaya Kouichi,
Matsuda Haruo
Publication year - 1989
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590030213
Subject(s) - chemistry , indium , dithiocarbamate , thermal decomposition , thermogravimetric analysis , sulfide , decomposition , inorganic chemistry , nuclear chemistry , organic chemistry
Thermal properties of organoindium thiolates were investigated by means of thermogravimetric (TG) and differential thermal (DT) analysis. Dibutyl‐indium propylthiolates (Bu n 2 InSPr n , Bu n 2 InSPr i , Bu i 2 InSPr n and Bu i 2 InSPr i ) decomposed up to 280°C along with an exothermic DT peak and gave indium(I) sulfide (InS) powders. Although the arylthiolate Bu n 2 InSPh also afforded InS powders, it decomposed at a slightly higher temperature. In contrast, the dithiolate and the dithiocarbamate complexes [Bu n In(SPr i ) 2 and In (S 2 CNBu 2 ) 3 ] gave indium(III) sulfide (In 2 S 3 ) powders.