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Linear trimerization of 1‐ethynylcyclohexan‐1‐ol catalysed by nickel(II) complexes
Author(s) -
Carusi P,
Cerichelli G,
Furlani A,
Russo M V,
Suber L
Publication year - 1987
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.590010610
Subject(s) - chemistry , trimer , nickel , catalysis , reaction mechanism , polymer chemistry , stereochemistry , organic chemistry , dimer
The catalytic reaction of 1‐ethynylcyclohexan‐1‐ol (EC) in the presence of bisphosphine nickel(II) complexes yields a linear trimer. The trimer could be isolated and characterized by means of MS, IR and NMR spectroscopies. The reaction mechanism is also discussed.