Regioselective phthalation and succinylation of  D ‐glucose and  D ‐galactose using protecting groups: Conversion of the products to organotin derivatives | Zendy

Patel Atula | Zendy; Poller Robert C | Zendy; Rathbone Elner B | Zendy

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Regioselective phthalation and succinylation of D ‐glucose and D ‐galactose using protecting groups: Conversion of the products to organotin derivatives

Author(s) -

Patel Atula,

Poller Robert C,

Rathbone Elner B

Publication year - 1987

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.590010406

Subject(s) - chemistry , succinic anhydride , succinylation , regioselectivity , phthalic anhydride , acylation , organic chemistry , galactose , protecting group , catalysis , biochemistry , amino acid , lysine , alkyl

1,2: 5,6‐Di‐ O ‐isopropylidene‐α‐ D ‐glucofuranose was acylated at the free 0‐3 position with phthalic and succinic anhydrides. Removal of the protecting groups gave the 3‐ O ‐acylglucopyranose compounds which were converted to their acetyl and organostannyl derivatives. A similar sequence of reactions was carried out with 1,2:3,4‐di‐ O ‐isopropylidene‐α‐ D ‐galactopyranose.

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