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A new 2D cadmium coordination polymer based on hydroxyl‐substituted benzenedicarboxylic acid as an effective heterogeneous catalyst for Knoevenagel condensation
Author(s) -
Sefidabi Farzaneh,
Abbasi Alireza,
Mortazavi SaeidehSadat,
MasteriFarahani Majid
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5890
Subject(s) - knoevenagel condensation , chemistry , thermogravimetric analysis , catalysis , infrared spectroscopy , coordination polymer , fourier transform infrared spectroscopy , condensation reaction , ligand (biochemistry) , polymer chemistry , inorganic chemistry , crystallography , crystal structure , nuclear chemistry , photochemistry , organic chemistry , chemical engineering , biochemistry , receptor , engineering
A self‐assembled new 2D cadmium network, [Cd (BDC‐OH)(DMF) 2 ·DMF] n (Cd‐BDC‐OH), was synthesized based on 2‐hydroxyterephthalic acid (BDC‐OH) ligand and utilized as a heterogeneous catalyst for Knoevenagel condensation. The structure was fully elucidated by single‐crystal X‐ray diffraction, Hirshfeld surface analysis, powder X‐ray diffraction, field emission‐scanning electron microscopy, Fourier transform‐infrared spectroscopy and thermogravimetric analysis. The fabricated coordination polymer exhibited high catalytic activity under ambient conditions, and was used without significant drop in product yield in further cycles.