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Electroreduction of Dy(III) assisted by Zn and its co‐deposition with Zn(II) in LiCl–KCl molten salt
Author(s) -
Li Wenlong,
Han Wei,
Li Mei,
Zhang Yongcheng,
Zhang Yingchun,
Yue Mengti,
Sun Yang
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5817
Subject(s) - chemistry , dysprosium , electrolysis , electrochemistry , molten salt , zinc , redox , cyclic voltammetry , inorganic chemistry , transition metal , analytical chemistry (journal) , electrode , electrolyte , organic chemistry , biochemistry , chromatography , catalysis
To recover dysprosium (Dy) from LiCl–KCl molten salt, the electrochemical mechanism of Dy(III) on liquid Zn electrode and co‐deposition of Dy(III) and Zn(II) on W electrode were studied using electrochemical methods. Cyclic voltammetry results demonstrated that the redox process of Dy on liquid Zn electrode is reversible and controlled by diffusion. Reverse chronopotentiograms showed that the transition time ratio of reduction and oxidation is ~3:1, revealing the redox of Dy on liquid Zn electrode is a kind of soluble–soluble system: Dy(III) + 3e − = (Dy–Zn) solution . The half‐wave potential of Dy(III) was almost constant with the increase in scanning rate. The electrochemical separation of metallic Dy from the molten salt was performed using constant potential electrolysis, and the product characterized using X‐ray diffraction and scanning electron microscopy–energy‐dispersive X‐ray spectroscopy was the thermodynamic unstable compound DyZn 5 . Also, the co‐deposition mechanism of Dy(III) and Zn(II) was explored, indicating that Dy(III) could deposit on pre‐deposited Zn and form Dy–Zn compounds: Zn(II) + 2e − = Zn and x Dy(III) + y Zn + 3 x e − = Dy x Zn y . Moreover, the effect of Dy(III) concentration on the formation of Dy–Zn compounds was investigated. The redox peak currents corresponding to different Dy–Zn compounds changed with the increase in Dy(III) concentration. The co‐deposition of Dy(III) and Zn(II) was performed using constant current electrolysis at diverse Dy(III) concentrations. The different Dy–Zn compounds were produced by controlling Dy(III) concentration.