Crystallographic report: A two‐dimensional layer structure containing calcium: [Ca 3 (1,3,5‐benzenetricarboxylate) 2 (H 2 O) 12 ]  n | Zendy

Yang YangYi | Zendy; Huang ZhongQi | Zendy; Szeto Lap | Zendy; Wong WingTak | Zendy

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Crystallographic report: A two‐dimensional layer structure containing calcium: [Ca 3 (1,3,5‐benzenetricarboxylate) 2 (H 2 O) 12 ] n

Author(s) -

Yang YangYi,

Huang ZhongQi,

Szeto Lap,

Wong WingTak

Publication year - 2004

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.580

Subject(s) - chemistry , crystal structure , crystallography , calcium , hydrogen bond , ion , chain (unit) , layer (electronics) , stereochemistry , bridging (networking) , molecule , organic chemistry , computer network , computer science , physics , astronomy

In the crystal structure, an eight‐coordinated calcium center is connected to adjacent seven‐coordinated calcium ions by a pair of µ‐aqua bridging ligands, leading to the formation of a chain, which is linked via benzenetricarboxylate ligands to neighboring chains to furnish a two‐dimensional layer structure. Layers are connected into a three‐dimensional structure facilitated by hydrogen bonding interactions. Copyright © 2004 John Wiley & Sons, Ltd.

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