Premium
Crystallographic report: A two‐dimensional layer structure containing calcium: [Ca 3 (1,3,5‐benzenetricarboxylate) 2 (H 2 O) 12 ] n
Author(s) -
Yang YangYi,
Huang ZhongQi,
Szeto Lap,
Wong WingTak
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.580
Subject(s) - chemistry , crystal structure , crystallography , calcium , hydrogen bond , ion , chain (unit) , layer (electronics) , stereochemistry , bridging (networking) , molecule , organic chemistry , computer network , computer science , physics , astronomy
In the crystal structure, an eight‐coordinated calcium center is connected to adjacent seven‐coordinated calcium ions by a pair of µ‐aqua bridging ligands, leading to the formation of a chain, which is linked via benzenetricarboxylate ligands to neighboring chains to furnish a two‐dimensional layer structure. Layers are connected into a three‐dimensional structure facilitated by hydrogen bonding interactions. Copyright © 2004 John Wiley & Sons, Ltd.