Premium
Development of a new catalytic and sustainable methodology for the synthesis of benzodiazepine triazole scaffold using magnetically separable CuFe 2 O 4 @MIL‐101(Cr) nano‐catalyst in aqueous medium
Author(s) -
Gupta Ajay,
Sarkar Fillip Kumar,
Sarkar Rajib,
Jamatia Ramen,
Lee Chang Yeon,
Gupta Gajendra,
Pal Amarta Kumar
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5782
Subject(s) - thermogravimetric analysis , catalysis , chemistry , x ray photoelectron spectroscopy , inductively coupled plasma , scanning electron microscope , fourier transform infrared spectroscopy , spectroscopy , infrared spectroscopy , analytical chemistry (journal) , nuclear chemistry , transmission electron microscopy , moiety , chemical engineering , nanotechnology , materials science , organic chemistry , composite material , physics , plasma , engineering , quantum mechanics
Magnetically retrieval CuFe 2 O 4 @MIL‐101(Cr) metal–organic framework was successfully prepared from easily available starting materials and characterized using various spectroscopic and analytical techniques such as powder X‐ray diffraction, scanning electron microscopy, energy dispersive X‐ray, transmission electron microscopy, elemental mapping, Fourier transform infrared spectroscopy, thermogravimetric analysis, X‐ray photoelectron spectroscopy, Brunauer–Emmett–Teller, vibrating sample magnetometer, and inductively coupled plasma optical emission spectroscopy. The catalyst was then used in the synthesis of benzodiazepines containing a triazole moiety in water. The advantages of this protocol include high yields, reusability of the catalyst, and gram‐scale synthesis.