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Crystallographic report: catena ‐Aqua(2,2′‐bipyrimidine)lithium(I) perchlorate
Author(s) -
Tong MingLiang,
Hu Sheng,
Yu XiaoLan,
Chen XiaoMing
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.577
Subject(s) - chemistry , basal plane , perchlorate , lithium (medication) , crystallography , hydrogen bond , molecule , ligand (biochemistry) , lithium perchlorate , nitrogen atom , stereochemistry , electrochemistry , ion , ring (chemistry) , organic chemistry , medicine , biochemistry , receptor , electrode , endocrinology
A lithium(I) coordination polymer has been formed from LiClO 4 and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd.