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Effective one‐pot synthesis of tetrahydrobenzo[ b ]pyran derivatives using nickel Schiff‐base complex immobilized on iron oxide nanoparticles
Author(s) -
Maleki Hossein,
Rakhtshah Jamshid,
Shaabani Behrouz
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5683
Subject(s) - thermogravimetric analysis , chemistry , catalysis , schiff base , pyran , inductively coupled plasma , nickel , fourier transform infrared spectroscopy , nickel oxide , nuclear chemistry , heterogeneous catalysis , nanoparticle , magnetic nanoparticles , inorganic chemistry , polymer chemistry , chemical engineering , organic chemistry , plasma , physics , quantum mechanics , engineering
Nickel Schiff‐base complex immobilized on silica‐coated Fe 3 O 4 as a heterogeneous catalyst was designed and characterized by different techniques, such as Fourier transform infrared (FT‐IR), X‐ray powder diffraction (XRD), field emission scanning electron microscopy (FE‐SEM), energy‐dispersive X‐ray spectroscopy (EDX), inductively coupled plasma (ICP) and vibrating sample magnetometry (VSM) thermogravimetric analysis (TGA), and Brunauer–Emmett–Teller (BET). The synthesized nanocatalyst has been explored as a new and efficient recyclable heterogeneous catalyst for the one‐pot three‐component synthesis of tetrahydrobenzo[ b ]pyran derivatives. The reaction proceeds smoothly to supply the respective products in excellent yields and low reaction times. The catalyst can be easily recovered by a magnetic field and reused for eight consecutive reaction cycles without significant loss of activity.