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Synthesis and catalytic properties of 1‐alkyl‐2‐imidazolineruthenium(II) complexes
Author(s) -
Özdemir İsmail,
Çetinkaya Bekir,
Demir Serpil,
Çetinkaya Engin,
Gürbüz Nevin,
Çiçek Metin
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.568
Subject(s) - chemistry , catalysis , alkyl , cycloisomerization , tosyl , imidazoline receptor , medicinal chemistry , organic chemistry , combinatorial chemistry , polymer chemistry , stereochemistry , medicine
New [RuCl 2 (imidazoline)(arene)] complexes have been prepared. The complexes were characterized by conventional spectroscopic methods and elemental analyses. Upon reaction with 1,1‐diphenylprop‐2‐ynol they generate catalyst precursors that can perform the cycloisomerization of diallyltosylamide into N ‐tosyl‐α‐methylenepyrrolidine. Copyright © 2004 John Wiley & Sons, Ltd.