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Crystallographic report: Aquadicylcohexyltin(IV) bis(2‐picolinate) ethanol solvate
Author(s) -
Dakternieks Dainis,
Duthie Andrew,
Smyth Douglas R.,
Stapleton Clynton P. D.,
Tiekink Edward R. T.
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.558
Subject(s) - chemistry , pentagonal bipyramidal molecular geometry , carboxylate , tin , crystallography , molecule , hydrogen bond , oxygen atom , oxygen , coordination geometry , atom (system on chip) , stereochemistry , crystal structure , organic chemistry , computer science , embedded system
The tin atom in the title compound is in a distorted pentagonal bipyramidal geometry defined by two sets of nitrogen and oxygen donors derived from the carboxylate ligands, two carbon atoms from the cyclohexyl substituents and an oxygen atom from the coordinated water molecule; CSnC 170.85(15)°. Extensive hydrogen bonding occurs in the lattice. Copyright © 2004 John Wiley & Sons, Ltd.