Impact of metalloporphyrin‐based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene | Zendy

Lü Xiangfei | Zendy; Du Yan xia | Zendy; Mele Giuseppe | Zendy; Li Jun | Zendy; Ni Wankui | Zendy; Zhao Yongguo | Zendy

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Impact of metalloporphyrin‐based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene

Author(s) -

Lü Xiangfei,

Du Yan xia,

Mele Giuseppe,

Li Jun,

Ni Wankui,

Zhao Yongguo

Publication year - 2020

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.5501

Subject(s) - chemistry , catalysis , polymer , porphyrin , crystallinity , polymer chemistry , scanning electron microscope , porosity , chemical engineering , organic chemistry , crystallography , materials science , engineering , composite material

Seven metalloporphyrin‐based porous coordination polymers: Fe ш (TZP)Poly ( CP1 ), Co II (TZP)Poly ( CP2 ), Ni II (TZP)Poly ( CP3 ), Cu II (TZP)Poly ( CP4 ), Zn II (TZP)Poly ( CP5 ), Mn II (TZP)Poly ( CP6 ), Pb II (TZP)Poly ( CP7 ) (TZP = 5,10,15,20‐ tetrakis[4‐(2,3,4,5‐tetrazolylphenyl)] porphyrin) were prepared and characterized. CP1−CP7 are amorphous aggregation supported with lower crystallinity by scanning electron microscopy, Brunauer−Emmett−Teller and powder X‐ray diffraction. These coordination polymers exhibit effective dye scavenging and catalytic activities toward the oxidation of alkylbenzene to ketones and can be reused by filtration with a slight decreasing of catalytic activities. Metal atoms metalloporphyrin polymers have a great influence on the catalytic activities of metalloporphyrin polymers.

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