Palladium‐catalysed cyclocarbonylation reactions in dimethyl carbonate, an eco‐friendly solvent and ring‐opening reagent | Zendy

Vasapollo Giuseppe | Zendy; Mele Giuseppe | Zendy; Maffei Annamaria | Zendy; Sole Roberta Del | Zendy

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Palladium‐catalysed cyclocarbonylation reactions in dimethyl carbonate, an eco‐friendly solvent and ring‐opening reagent

Author(s) -

Vasapollo Giuseppe,

Mele Giuseppe,

Maffei Annamaria,

Sole Roberta Del

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.543

Subject(s) - chemistry , dimethyl carbonate , reagent , solvent , phenol , ring (chemistry) , environmentally friendly , palladium , organic chemistry , catalysis , carbonate , ecology , biology

Dimethyl carbonate (DMC) is used as an alternative and eco‐friendly solvent for selective cyclocarbonylation reactions of allyl phenol derivatives for the synthesis of lactones; in some cases, depending on the reaction condition, DMC behaves as a ring‐opening reagent producing methoxycarbonyl compounds. Copyright © 2003 John Wiley & Sons, Ltd.

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