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Cobalt‐based catalytic system for the chemical fixation of CO 2 under solvent‐free conditions
Author(s) -
Wu Fengtian,
Lin Yu
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5427
Subject(s) - chemistry , cobalt , catalysis , solvent , fixation (population genetics) , combinatorial chemistry , organic chemistry , biochemistry , gene
Abstract We have described a novel and efficient method for synthesizing cyclic carbonates with ‘Co (NO 3 ) 2 . 6H 2 O/ L6 ’‐catalyzed coupling of epoxides and CO 2 under solvent‐free conditions. We proposed a possible reaction mechanism based on some control experiments. Phenylpropiolic acid could be provided by using the same method.