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Dichloroimidazolidinedione‐activated one‐pot Suzuki–Miyaura cross‐coupling of phenols
Author(s) -
Madankar Kamelia,
Mokhtari Javad,
Mirjafary Zohreh
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5383
Subject(s) - chemistry , phenols , aryl , reagent , tetrahydrofuran , suzuki reaction , boronic acid , organic chemistry , coupling reaction , combinatorial chemistry , coupling (piping) , catalysis , mechanical engineering , alkyl , solvent , engineering
The first general method for the Suzuki‐type cross‐coupling of phenols with aryl boronic acids using dichloroimidazolidinedione (DCID) as a new reagent is presented. In the presence of DCID and Pd/metal–organic framework (MOF), coupling of aryl boronic acids with a wide range of phenols, was carried out smoothly in tetrahydrofuran (THF) at reflux conditions to afford the cross‐coupling products in good to excellent yields. The structures of all compounds were corroborated by 1 H‐ and 13 C‐NMR. A plausible mechanism for this type of reaction is proposed.