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Design and synthesis of the honeycomb PtSnNa/ZSM‐5 monolithic catalyst for propane dehydrogenation
Author(s) -
Tong Qing,
Zhao Shiyong,
Liu Yubing,
Xu Bolian,
Yu Lei,
Fan Yining
Publication year - 2020
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5380
Subject(s) - catalysis , dehydrogenation , chemistry , propane , selectivity , zsm 5 , chemical engineering , honeycomb , organic chemistry , zeolite , composite material , materials science , engineering
A novel PtSnNa/ZSM‐5 monolithic catalyst was designed and synthesized for the propane dehydrogenation reaction, which was a significant transformation in industry. Experimental results showed that although the propane conversion and the propylene selectivity gradually fell down along with the reaction time, the descent speed of the PtSnNa/ZSM‐5 monolithic catalyst was slower than that of the granule catalyst and the propane conversion and propylene selectivity of the reaction with monolithic catalyst still remained at a high level after 12 hr. The monolithic catalyst had regular pore structure that facilitated the separation of the product from the catalyst and reduced the limitation on internal and external diffusion and mass transfer, and led to the high catalytic activity and stability. The catalyst could be easily fabricated and was of highly industrial application potential.