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Crystallographic report: Bis(tetraphenylphosphonium) bis(dichloro‐nitratophenylstannate)methane, [Ph 4 P + ] 2 [(PhCl 2 (NO 3 )Sn) 2 CH 2 ] 2−
Author(s) -
Jurkschat Klaus,
Reeske Gregor,
Schürmann Marcus,
Tiekink Edward R. T.
Publication year - 2003
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.526
Subject(s) - chemistry , tin , denticity , intramolecular force , crystallography , atom (system on chip) , methane , stereochemistry , crystal structure , organic chemistry , computer science , embedded system
Each tin atom of the title compound is five‐coordinate, defined by 2C, 2Cl and 1O atoms, and shows a distorted square pyramidal configuration stabilized by intramolecular Sn· · ·O or Sn· · ·Cl interactions. Both nitrate anions coordinate the tin atoms in a monodentate mode. Copyright © 2003 John Wiley & Sons, Ltd.