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Crystallographic report: (2,2′‐Bipyridyl)bis(ethanoldithiocarbamato)zinc(II)
Author(s) -
Saravanan M.,
Ramalingam K.,
Bocelli G.,
Cantoni A.
Publication year - 2004
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.525
Subject(s) - chemistry , dithiocarbamate , denticity , chromophore , zinc , crystallography , square pyramidal molecular geometry , valence (chemistry) , stereochemistry , crystal structure , photochemistry , organic chemistry
Abstract Zn(meadtc) 2 (2,2′‐bipy) is a ZnS 3 N 2 chromophore with a distorted square pyramidal geometry. The IR band at 1002 cm −1 and the bond valence sum value of 1.98 confirmed the monodentate dithiocarbamate in coordination. The non‐bonding Zn–S distance is 5.004(3) Å. Copyright © 2004 John Wiley & Sons, Ltd.