Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts | Zendy

Imakura Yasuo | Zendy; Nishiguchi Satoru | Zendy; Orita Akihiro | Zendy; Otera Junzo | Zendy

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Assessment of fluoroalkyltin compounds as fluorous Lewis acid catalysts

Author(s) -

Imakura Yasuo,

Nishiguchi Satoru,

Orita Akihiro,

Otera Junzo

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.517

Subject(s) - chemistry , lewis acids and bases , catalysis , fluorocarbon , solubility , lewis acid catalysis , organic chemistry , combinatorial chemistry

The synthesis of a variety of organotin compounds with 1 H , 1 H , 2 H , 2 H ‐perfluorooctyl groups is reported, together with an improved method for the corresponding distannoxane. Unique properties of this compound are disclosed in terms of fluorophilicity and activity as a Lewis acid catalyst in comparison with other mono‐nuclear derivatives. A new criterion for obtaining high solubility in fluorocarbon solvents is presented. Copyright © 2003 John Wiley & Sons, Ltd.

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