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A Recyclable bi‐functional Luminescent Zinc (II) metal–organic framework as highly selective and sensitive sensing probe for nitroaromatic explosives and Fe 3+ ions
Author(s) -
Gao Enjun,
Liu Dongsheng,
Xing Jialing,
Feng Yunhui,
Su Junqi,
Liu Jiaxing,
Zhao Hongwei,
Wang Ning,
Jia Zhili,
Zhang Xiaoyin,
Fedin Vladimir P.,
Zhu Mingchang
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.5109
Subject(s) - chemistry , nitro , benzoic acid , detection limit , resorcinol , metal ions in aqueous solution , metal organic framework , selectivity , ligand (biochemistry) , fluorescence , luminescence , quenching (fluorescence) , zinc , inorganic chemistry , metal , nuclear chemistry , combinatorial chemistry , organic chemistry , catalysis , chromatography , biochemistry , alkyl , receptor , physics , optoelectronics , adsorption , quantum mechanics
By introducing carboxyl tag to the aromatic ligands system and borrowing the organic template open framework idea, a stable fluorescent Zn metal–organic framework was successfully prepared through a rigid ligand H 6 L (3,5‐bis‐(3‐carboxyphenoxy)benzoic acid) under hydrothermal conditions. The selectivity and sensitivity of the Zn‐MOF to metal ions and nitro‐aromatic compounds (NACs) were investigated by fluorescence quenching. And the Zn‐MOF showed a high sensibility of nitro‐aromatic compounds (NACs) and Fe 3+ ions, especially for 4‐(4‐nitropheny lazo) resorcinol (NPLR). More importantly, the detection limit of the Zn‐MOF for detecting NPLR solution was found to be 1.71 ppb. Moreover, this sensor is remarkable recyclable and is promisingly applied for rapid, on‐site and sensing of explosive residuals.