Iron (III)‐porphyrin Complex FeTSPP as an efficient catalyst for synthesis of tetrazole derivatives  via  [2 + 3]cycloaddition reaction in aqueous medium | Zendy

ElRemaily Mahmoud Abd El Aleem Ali Ali | Zendy; Elhady O.M. | Zendy

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Iron (III)‐porphyrin Complex FeTSPP as an efficient catalyst for synthesis of tetrazole derivatives via [2 + 3]cycloaddition reaction in aqueous medium

Author(s) -

ElRemaily Mahmoud Abd El Aleem Ali Ali,

Elhady O.M.

Publication year - 2019

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.4989

Subject(s) - chemistry , cycloaddition , tetrazole , catalysis , porphyrin , aqueous medium , azide , yield (engineering) , aqueous solution , click chemistry , chloride , combinatorial chemistry , organic chemistry , materials science , metallurgy

The metal complex (5,10,15,20‐tetrakis‐(4‐sulfonatophenyl)‐porphyrin‐iron (III) chloride (FeTSPP) was new employed in an environmentally benign protocol as an efficient catalyst for a “click” chemistry approach for the synthesis of tetrazole and guanindinyltetrazole derivatives via [2 + 3] cycloaddition reaction of nitriles and azide derivatives in aqueous medium. The synthesized compounds were obtained in excellent yield, short reaction times and a recoverable catalyst.

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