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NHC copper complexes functionalized with sulfoxide and sulfone moieties
Author(s) -
Szadkowska Anna,
Pawłowski Robert,
Zaorska Ewelina,
Staszko Sebastian,
Trzybiński Damian,
Woźniak Krzysztof
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4983
Subject(s) - chemistry , sulfone , sulfoxide , hydroboration , copper , carbene , cycloaddition , polymer chemistry , catalysis , ligand (biochemistry) , combinatorial chemistry , organic chemistry , biochemistry , receptor
A series of N ‐heterocyclic copper carbene complexes bearing sulfoxide and sulfone moieties have been prepared. In case of new copper compounds with sulfone ligand, the solid‐state structures were determined using X‐Ray crystallography. Obtained complexes were investigated as catalysts in such transformations as: 1,3‐dipolar cycloaddition of alkynes and azides (CuAAC), A 3 coupling reaction and β‐hydroboration and compared with standard copper catalytic systems.