Crystallographic report: Bis[3‐(tri‐ p ‐tolyl)germyl‐3‐( o ‐tolyl)‐propionato]dibutyltin(IV) | Zendy

Mazhar M. | Zendy; Dastgir Sarim | Zendy; Mahon Mary F. | Zendy; Molloy Kieran C. | Zendy

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Crystallographic report: Bis[3‐(tri‐ p ‐tolyl)germyl‐3‐( o ‐tolyl)‐propionato]dibutyltin(IV)

Author(s) -

Mazhar M.,

Dastgir Sarim,

Mahon Mary F.,

Molloy Kieran C.

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.493

Subject(s) - chemistry , tin , carboxylate , bipyramid , crystallography , germanium , crystal structure , chelation , atom (system on chip) , stereochemistry , trigonal bipyramidal molecular geometry , monomer , tetrahedral molecular geometry , inorganic chemistry , silicon , organic chemistry , computer science , embedded system , polymer

The crystal structure of [( p ‐CH 3 C 6 H 4 ) 3 GeCH( o ‐CH 3 C 6 H 4 )CH 2 CO 2 ] 2 Sn(C 4 H 9 ) 2 consists of a monomer with the atoms of tin and germanium both occupying tetrahedral geometries. However, the tin atom is distorted towards a skew trapezoidal bipyramid geometry as a result of weakly chelating carboxylate ligands. Copyright © 2003 John Wiley & Sons, Ltd.

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