Crystallographic report: Triorganotin 2‐( p ‐chlorophenyl)‐3‐methylbutyrates | Zendy

Song Xueqing | Zendy; Cahill Christopher | Zendy; Eng George | Zendy

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Crystallographic report: Triorganotin 2‐( p ‐chlorophenyl)‐3‐methylbutyrates

Author(s) -

Song Xueqing,

Cahill Christopher,

Eng George

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.492

Subject(s) - chemistry , carboxylate , trigonal bipyramidal molecular geometry , crystallography , crystal structure , tetrahedron , oxygen atom , trigonal crystal system , stereochemistry , group (periodic table) , crystal (programming language) , molecule , organic chemistry , computer science , programming language

The crystal structures of two triorganotin butyrates were determined. Tricyclohexyltin 2‐( p ‐chlorophenyl)‐3‐methylbutyrate was determined to have a distorted tetrahedral geometry. Trimethyltin 2‐( p ‐chlorophenyl)‐3‐methylbutyrate, on the other hand, was found to be polymeric in nature with a trigonal bipyramidal configuration. The three methyl groups are located in the equatorial positions with the axial positions occupied by oxygen atoms from two different carboxylate groups. Copyright © 2003 John Wiley & Sons, Ltd.

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