Crystallographic report: Thallium(18‐crown‐6) hexafluorophosphate, [Tl(18‐crown‐6)](PF 6 ) | Zendy

Liu Fenghui | Zendy

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Crystallographic report: Thallium(18‐crown‐6) hexafluorophosphate, [Tl(18‐crown‐6)](PF 6 )

Author(s) -

Liu Fenghui

Publication year - 2003

Publication title -

applied organometallic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.53

H-Index - 71

eISSN - 1099-0739

pISSN - 0268-2605

DOI - 10.1002/aoc.482

Subject(s) - hexafluorophosphate , thallium , chemistry , crown (dentistry) , crystallography , 18 crown 6 , fluorine , oxygen atom , x ray crystallography , crystal structure , stereochemistry , diffraction , inorganic chemistry , ion , molecule , organic chemistry , optics , catalysis , physics , ionic liquid , medicine , dentistry

Thallium(18‐crown‐6) hexafluorophosphate was prepared and its structure was determined by X‐ray diffraction analysis. The Tl + ion is surrounded by six oxygen atoms of 18‐crown‐6 and three fluorine atoms of $\hbox{PF}_{6}^{-}$ , forming a sandwiched structure. If the three Tl–F interactions were considered significant, the coordination number in the title compound would be nine. Copyright © 2003 John Wiley & Sons, Ltd.

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