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Applications of inorganic‐organic hybrid architectures based on polyoxometalates in catalyzed and photocatalyzed chemical transformations
Author(s) -
Lotfian Nahid,
Heravi Majid M.,
Mirzaei Masoud,
Heidari Bahareh
Publication year - 2019
Publication title -
applied organometallic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.53
H-Index - 71
eISSN - 1099-0739
pISSN - 0268-2605
DOI - 10.1002/aoc.4808
Subject(s) - chemistry , catalysis , photocatalysis , scope (computer science) , selectivity , polyoxometalate , hybrid material , combinatorial chemistry , metal , organic synthesis , rational design , heterogeneous catalysis , organic chemistry , nanotechnology , materials science , computer science , programming language
The scope of this article is to reveal the fruitful combination of POM species with metal coordination complexes, leading to the construction of several efficient multifunctional catalysts. In this review, we try to underscore various catalytic and photocatalytic reactions catalyzed by POM‐based inorganic‐organic hybrid. Notably, it has been well established that depending on the type of the reaction, the activity and selectivity of these hybrid catalyst can be drastically improved by the rational and correct choice of the organic metal complex and POM anion providing a marriage of convenience.